It's certainly not a bad idea. You might not get the benefit of modern I/O networking (ProfiNet, Ethernet/IP, EtherCat, etc), depending on what the Scorbot supports. But I imagine that using an old robot like that will force you to learn a lot about the nuts&bolts end of the robots.
Rather than invest in a modern PLC, I would suggest looking into CodeSys. The "free" version is non-crippled, aisde from requiring a reboot every 2hrs. You can also get a non-commercial license to run in on a Raspberry Pi for $35, last I checked. That would save you the potential issues of having to deal with one of the major PLC brands and their required extra bits. You can then use almost any eBay network I/O device, and generate your discrete bit-banged I/O between the PLC and Scorbot.